Microwave-assisted synthesis of α-aminophosphine oxides

Tripolszky, Anna and Bálint, Erika and Keglevich, György (2019) Microwave-assisted synthesis of α-aminophosphine oxides. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 194 (4-6). pp. 345-348. ISSN 1042-6507

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Abstract

Aminophosphine oxides and bis(phosphinoylmethyl)amines were synthesized by the microwave (MW)-assisted Kabachnik-Fields reaction of primary amines, paraformaldehyde and secondary phosphine oxides. The bisphosphines obtained after deoxygenation of the bis(phosphinoymethyl)- amine derivatives were utilized in the synthesis of cyclic transition metal complexes.

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