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Evidence for Ag participating the electrochemical migration of 96.5Sn-3Ag-0.5Cu alloy

Zhong, Xiankang and Lu, Wenjun and Liao, Bokai and Bálint, Medgyes and Junying, Hu and Yan, Zheng and Dezhi, Zeng and Zhi, Zhang (2019) Evidence for Ag participating the electrochemical migration of 96.5Sn-3Ag-0.5Cu alloy. CORROSION SCIENCE. ISSN 0010-938X

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Abstract

Ag participating the electrochemical migration (ECM) of Sn-Ag based alloys is still controversial. In this work,Ag+concentration in electrolyte layer and Ag distribution in dendrites formed during the ECM of 96.5Sn-3Ag-0.5Cu alloy were investigated using Inductively Coupled Plasma Source Mass Spectrometer and ScanningTransmission Electron Microscopy, respectively. Results show that Ag+can only be detected when Ag can re-lease from Ag3Sn during the anodic polarization of 96.5Sn-3Ag-0.5Cu alloy. Under such a condition, Ag couldalso be found in dendrites. Therefore, it can be concluded that Ag participates the ECM of 96.5Sn-3Ag-0.5Cualloy, but it is potential-dependent.

Item Type: Article
Subjects: T Technology / alkalmazott, műszaki tudományok > TP Chemical technology / vegyipar, vegyészeti technológia
Depositing User: Dr. Bálint Medgyes
Date Deposited: 19 Dec 2019 15:19
Last Modified: 03 Apr 2023 06:40
URI: http://real.mtak.hu/id/eprint/104634

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