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Energetics of ion selectivity in slit-like pores

Valiskó, Mónika and Boda, Dezső and Nagy, Tímea and Henderson, Douglas (2009) Energetics of ion selectivity in slit-like pores. In: 60th Annual Meeting of the International Society of Electrochemistry, 2009. Augusztus 14.-22., Peking, Kína.

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Abstract

We study the effect of the charge and/or size asymmetry, we show results for a wide range of electrode charge and we study the effect of charge and size asymmetry on the electrode potential, and the competition of two cations of different size and valence near a highly charged electrode. If the ions have different diameters and/or valences, the electrode potential is nonzero even if the electrode charge is zero (PZC potential). Size and valence asymmetries are two competing effects regarding the sign and magnitude of the PZC potential.

Item Type: Conference or Workshop Item (Poster)
Subjects: Q Science / természettudomány > QD Chemistry / kémia > QD02 Physical chemistry / fizikai kémia
Depositing User: DR. Mónika Valiskó
Date Deposited: 12 Sep 2014 10:51
Last Modified: 03 Apr 2023 07:58
URI: http://real.mtak.hu/id/eprint/14844

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