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Self-recognition in the liquid-phase hydrogenation of an optically active compound over Pd/SiO2 catalysts

Pálinkó, István and Notheisz, Ferenc and Bartók, Mihály and Ostgard, D. and Smith, G. V. (1990) Self-recognition in the liquid-phase hydrogenation of an optically active compound over Pd/SiO2 catalysts. Journal of Molecular Catalysis, 57 (3). pp. 353-359. ISSN 0304-5102 (print); 1873-3131 (online)

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Abstract

In the reactions of (+)-apopinene (1) in the presence of hydrogen, an optically active hydrocarbon-like layer forms over the surface of Pd catalysts. It is suggested that this layer adsorbs one isomer preferentially, and that it provides the sites for both isomerization and hydrogenation.

Item Type: Article
Subjects: Q Science / természettudomány > QD Chemistry / kémia
Depositing User: Erika Bilicsi
Date Deposited: 20 Sep 2012 06:22
Last Modified: 25 Sep 2012 08:10
URI: http://real.mtak.hu/id/eprint/3025

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