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Mixed-metal pillared layer clays and their pillaring precursors

Pálinkó, István and Molnár, Árpád and Nagy, J. B. and Lázár, Károly and Valyon, József and Kiricsi, Imre (1997) Mixed-metal pillared layer clays and their pillaring precursors. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 93 (8). pp. 1591-1599. ISSN 0956-5000

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Abstract

Mixed-metal pillared layer clays (Fe,Al-PILCs and Cr,Al-PILCs) of various compositions and the pillaring precursors have been prepared and characterised with a combination of chemical and instrumental methods. Chemical analysis data, IR, (57)Mossbauer and Al-27 NMR spectroscopic measurements on the precipitated pillaring precursors and comparison of redox behaviour [temperature-programmed reduction (TPR) results and Fe-57 Mossbauer measurements on the heat-treated and the reduced samples] of the ion-exchanged and Al-pillared and mixed-metal pillared clays revealed that isomorphous substitution of Al for Fe or Cr did not occur in either the tetrahedral or the octahedral positions. Heat treatment, however, resulted in mixed-metal pillared clays which were active in both acid- catalysed and redox transformations.

Item Type: Article
Subjects: Q Science / természettudomány > QC Physics / fizika
Q Science / természettudomány > QD Chemistry / kémia
Q Science / természettudomány > QD Chemistry / kémia > QD02 Physical chemistry / fizikai kémia
SWORD Depositor: MTMT SWORD
Depositing User: MTMT SWORD
Date Deposited: 28 May 2013 13:36
Last Modified: 23 Jul 2013 12:02
URI: http://real.mtak.hu/id/eprint/5330

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