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Continuous Flow Alcoholysis of Dialkyl H-Phosphonates with Aliphatic Alcohols

Bálint, Erika and Tajti, Ádám and Tóth, Nóra and Keglevich, György (2018) Continuous Flow Alcoholysis of Dialkyl H-Phosphonates with Aliphatic Alcohols. MOLECULES, 23. pp. 1618-1633. ISSN 1420-3049

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Abstract

The continuous flow alcoholysis of dialkyl H-phosphonates by aliphatic alcohols in the absence of a catalyst was elaborated using a microwave (MW) reactor equipped with a flow cell. By the precise control of the reaction conditions, the synthesis could be fine-tuned towards dialkyl H-phosphonates with two different and with two identical alkyl groups. In contrast to the “traditional” batch alcoholysis, flow approaches required shorter reaction times, and the products became available at a larger scale.

Item Type: Article
Subjects: Q Science / természettudomány > QD Chemistry / kémia
Q Science / természettudomány > QD Chemistry / kémia > QD04 Organic chemistry / szerves kémia
Depositing User: Dr. Erika Bálint
Date Deposited: 30 Sep 2018 05:29
Last Modified: 30 Sep 2018 05:29
URI: http://real.mtak.hu/id/eprint/85741

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