Dealouche, Thomas and Mocanu, Annabella and Roisnel, Thierry and Szűcs, Rózsa and Emmanuel, Jacques and Benkő, Zoltán and Nyulászi, László and Bouit, Pierre-Antoine and Hissler, Muriel (2019) Pi-extended phosphepines: redox and optically active P-heterocycles with non-planar framework. Organic Letters. ISSN 1523-7060
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Abstract
In this letter, we present the synthesis of a new family of -extended dithieno[b,f]phosphepines. The Pd-catalyzed direct-arylation allows the introduction of various substituents, which tune the absorption/emission in the visible range as well as the redox properties. All those modifications were rationalized through DFT calculations. The physical properties of ambipolar phosphepine with diphenylamino substituents conduct us to use it as a semi-conductor in a p-type organic field-effect transis-tors (OFETs).
| Item Type: | Article |
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| Subjects: | Q Science / természettudomány > QD Chemistry / kémia > QD03 Inorganic chemistry / szervetlen kémia |
| Depositing User: | Nyulaszi laszlo |
| Date Deposited: | 15 Feb 2019 09:00 |
| Last Modified: | 15 Feb 2019 09:00 |
| URI: | http://real.mtak.hu/id/eprint/91322 |
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