Microwave-Assisted Organophosphorus Syntheses

Keglevich, György and Grün, Alajos and Bálint, Erika and Kiss, Nóra Zsuzsa and Jablonkai, Erzsébet (2013) Microwave-Assisted Organophosphorus Syntheses. Current Organic Chemistry, 17. p. 545. ISSN 1385-2728

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Abstract

The spread of microwave (MW) equipment has brought about a tremendous development in synthetic organic chemistry. This environmentally friendly methodology, associated often with solventless conditions, has also had a positive impact on organophosphorus chemistry, allowing new reactions to be carried out, or increasing the rate, selectivity and yield. In special cases, MW irradiation may replace phase transfer or other kinds of catalysts. Reactions, such as the derivatization of phosphinic acids, the inverse Wittig protocol, Diels– Alder cycloadditions, fragmentation-related phosphorylations, phospha-Michael additions, Kabachnik–Fields condensations, the addition of >P(O)H species to carbonyl compounds, substitution of

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