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Utilization of copper on iron catalyst for the synthesis of biaryl systems and benzoxazines via oxidative arylation of anilide derivatives

Székely, Anna and Sinai, Ádám and Tóth, Edina and Zoltán, Novák (2015) Utilization of copper on iron catalyst for the synthesis of biaryl systems and benzoxazines via oxidative arylation of anilide derivatives. Synthesis. ISSN 0039-7881 (Submitted)

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Abstract

Heterogeneous copper on iron catalyst serves as an efficient alternative copper source for arylation reactions using hypervalent iodonium salts. The copper (0) catalyst affords meta - arylation of pivalanilides, while 2 - ethy nylanilides undergo oxidative carboarylation - ring closure with diaryliodonium salts.

Item Type: Article
Subjects: Q Science / természettudomány > QD Chemistry / kémia > QD04 Organic chemistry / szerves kémia
Depositing User: Dr. Zoltán Novák
Date Deposited: 10 Feb 2015 13:09
Last Modified: 03 Apr 2023 08:25
URI: http://real.mtak.hu/id/eprint/21498

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