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Regioselective Suzuki–Miyaura Cross-Coupling Reactions of the Bis(triflate) of 1,4-Dihydroxy-9H-fluoren-9-one

Sonneck, Marcel and Kuhrt, David and Kónya, Krisztina Emília and Patonay, Tamás and Villinger, Alexander and Langer, Peter (2015) Regioselective Suzuki–Miyaura Cross-Coupling Reactions of the Bis(triflate) of 1,4-Dihydroxy-9H-fluoren-9-one. SYNLETT, 27 (01). pp. 75-79. ISSN 0936-5214

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Abstract

1,4-Diaryl-9H-fluoren-9-ones were prepared by regioselective Suzuki–Miyaura cross-coupling reaction of the bis(triflate) of 1,4-dihydroxy-9H-fluoren-9-one. The reactions proceeded with excellent site selectivity. The first attack occurs at position 1, due to electronic reasons

Item Type: Article
Uncontrolled Keywords: Catalysis - Suzuki–Miyaura reaction - regioselectivity - palladium - heterocycles
Subjects: Q Science / természettudomány > QD Chemistry / kémia > QD04 Organic chemistry / szerves kémia
Depositing User: Krisztina Kónya
Date Deposited: 25 Dec 2015 18:34
Last Modified: 25 Dec 2015 18:34
URI: http://real.mtak.hu/id/eprint/31334

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