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A New Access Route to Functionalized Cispentacins from Norbornene b-Amino Acids

Kiss, Loránd and Cherepanova, Maria and Forró, Enikő and Fülöp, Ferenc (2013) A New Access Route to Functionalized Cispentacins from Norbornene b-Amino Acids. CHEMISTRY-A EUROPEAN JOURNAL, 19. pp. 2102-2107. ISSN 0947-6539

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Abstract

An efficient and simple new stereocontrolled access route to novel disubstituted cispentacin derivatives with multiple stereogenic centers from norbornene b-lactam has been developed. The synthesis involves olefinic bond functionalization by dihydroxylation followed by oxidative ring cleavage and transformation of the dialdehyde intermediate through a Wittig reaction.

Item Type: Article
Subjects: Q Science / természettudomány > QD Chemistry / kémia > QD04 Organic chemistry / szerves kémia
Depositing User: Dr Loránd Kiss
Date Deposited: 30 Dec 2015 19:44
Last Modified: 31 Dec 2015 09:42
URI: http://real.mtak.hu/id/eprint/31581

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