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Solid-liquid phase C-alkylation of active methylene containing compounds under microwave conditions

Grün, Alajos and Bálint, Erika and Keglevich, György (2015) Solid-liquid phase C-alkylation of active methylene containing compounds under microwave conditions. CATALYSTS, 5 (2). pp. 634-652. ISSN 2073-4344

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Abstract

The solid–liquid phase C-alkylation of active methylene containing compounds with C=O or P=O functions under phase transfer catalysis or microwave conditions has been summarized in this minireview. The mono- and dialkylation of the methylene containing derivatives was investigated under microwave (MW) conditions. It was found that in many cases, there was no need to use phase transfer catalyst under MW conditions. Moreover, most of the reactions were carried out without any solvent. These results mean a serious green chemical advantage. © 2015 by the authors; licensee MDPI, Basel, Switzerland.

Item Type: Article
Uncontrolled Keywords: solvent-free reaction; phase transfer catalysis; MICROWAVE IRRADIATION; green synthesis; Compounds with active methylene group; C-ALKYLATION
Subjects: Q Science / természettudomány > QD Chemistry / kémia > QD04 Organic chemistry / szerves kémia
T Technology / alkalmazott, műszaki tudományok > TP Chemical technology / vegyipar, vegyészeti technológia
SWORD Depositor: MTMT SWORD
Depositing User: MTMT SWORD
Date Deposited: 10 Feb 2016 08:11
Last Modified: 10 Feb 2016 08:11
URI: http://real.mtak.hu/id/eprint/33208

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