Magnetic monitoring, geochemical and mineralogical analysis of settled dust from North and Central Transdanubia, Hungary

Márton, Emő and Zajzon, Norbert and Lautner, Péter and Sipos, Péter and Szentmarjay, Tibor and Pethe, Mihály (2012) Magnetic monitoring, geochemical and mineralogical analysis of settled dust from North and Central Transdanubia, Hungary. Central European Geology, 55 (4). pp. 347-364. ISSN 1788-2281

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Abstract

Abstract Ferromagnetic grains in airborne dust are important indicators of vehicle traffic, some industrial sources and combustion/heating. Settled dust consists mainly of diamagnetic material; therefore accessory ferromagnetic grains are readily indicated by magnetic measurements. In this paper settled dust samples collected on a monthly basis in the years 2008–2011 were studied. Non-destructive magnetic measurements were followed by geochemical and mineralogical analyses. In selected samples we identified airborne anthropogenic materials (e.g. silicate and magnetite spherules), minerals from the natural environment and organic material. Seasonally appearing materials (e.g. soot in winter, plant fragments and pollen in summer) increased the mass of the settled dust, but not the magnetic susceptibility. Thus, we realized that the generally interpreted mass susceptibility in environmental magnetic studies would not always appropriately characterize the magnetic pollution. In the interpretation we gave preference to total susceptibility because of its direct connection to the pollution, except in comparison with metal concentrations. Trends in magnetic pollution were eventually analyzed for 19 sampling sites. Irrespective of the degree and source of the pollution the monthly variation curves of magnetic susceptibility exhibit a general maximum (March-April), followed by gradual decrease. A corresponding peak is observed in the amounts of dust. Both can be explained by re-suspension of dust settled in winter. The additional maxima in the mass of the dust (June and August, respectively) are probably due to contribution from vegetation and/or an artifact from algaecide. For three key sampling sites comparison was made between the concentrations of 12 metals and the respective mass susceptibilities and good linear correlation was found for Fe, Mn and Zn for all, for Cr, Cu, Pb, V, Ba, Sr and Zr for two sampling sites. Cd, which is enriched in all samples, does not correlate with the magnetic susceptibility.

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