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Slow Charging/Discharging Processes of the Electrochemical Double Layer

Pajkossy, Tamás (2018) Slow Charging/Discharging Processes of the Electrochemical Double Layer. BULGARIAN CHEMICAL COMMUNICATIONS, 50D. pp. 90-98. ISSN 0861-9808

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Abstract

It is demonstrated for two cases of apparently ideal, ideally polarizable electrochemical interfaces that chargingdischarging following potential changes is not instantaneous hence the double layer is not (solely) of electrostatic nature – as assumed in „classical” double layer theories. That is, physico-chemical interactions must also be considered to account for the slow double layer rearrangement processes.

Item Type: Article
Uncontrolled Keywords: double layer, impedance, capacitance, kinetics, ionic liquids, single crystal
Subjects: Q Science / természettudomány > QD Chemistry / kémia > QD02 Physical chemistry / fizikai kémia
Depositing User: Tamás Pajkossy
Date Deposited: 08 Jan 2019 12:59
Last Modified: 05 Apr 2023 07:54
URI: http://real.mtak.hu/id/eprint/89314

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