REAL

Low temperature formation of copper rich silicides

Dodony, Erzsébet and Radnóczi, György Z. and Dódony, István (2019) Low temperature formation of copper rich silicides. Intermetallics, 107. pp. 108-115. ISSN 0966-9795

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Abstract

The reactions of copper and amorphous silicon were studied by in-situ transmission electron microscopy up to 500 degrees C. Only the Cu76Si24-eta phase and the Cu82Si18-delta phase formed at this temperature. The crystal structure of the dominating Cu76Si24 changed, by the elapsed time after heating. The Cu-Si ordering resulted in different supercells, built up by topologically identical subcells with different site occupancies and arrangement. Two modulated crystal structures were solved based on diffraction data and HRTEM images.

Item Type: Article
Uncontrolled Keywords: Copper-silicide; Crystal structure; Modulation; Electron crystallography
Subjects: Q Science / természettudomány > QD Chemistry / kémia > QD02 Physical chemistry / fizikai kémia
SWORD Depositor: MTMT SWORD
Depositing User: MTMT SWORD
Date Deposited: 09 Apr 2019 08:48
Last Modified: 09 Apr 2019 08:48
URI: http://real.mtak.hu/id/eprint/92633

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