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Synthesis of novel fluorinated building blocks via halofluorination and related reactions

Remete, Attila Márió and Novák, Tamás and Nonn, Melinda (2020) Synthesis of novel fluorinated building blocks via halofluorination and related reactions. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 16. pp. 2562-2575. ISSN 1860-5397

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Abstract

A study exploring halofluorination and fluoroselenation of some cyclic olefins, such as diesters, imides, and lactams with varied functionalization patterns and different structural architectures is described. The synthetic methodologies were based on electrophilic activation through halonium ions of the ring olefin bonds, followed by nucleophilic fluorination with Deoxo-Fluor®. The fluorine- containing products thus obtained were subjected to elimination reactions, yielding various fluorine-containing small-molecular entities.

Item Type: Article
Subjects: Q Science / természettudomány > QD Chemistry / kémia > QD04 Organic chemistry / szerves kémia
Depositing User: Dr Loránd Kiss
Date Deposited: 23 Nov 2020 09:00
Last Modified: 03 Apr 2023 07:04
URI: http://real.mtak.hu/id/eprint/117244

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