Szuroczki, Péter and Molnár, Levente and Dörnyei, Ágnes and Kollár, László (2020) Facile, High-Yielding Synthesis of 4-Functionalised 1,2,3- Triazoles via Amino- and Aryloxycarbonylation. CHEMISTRY SELECT, 5 (2). pp. 448-451. ISSN 2365-6549
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Abstract
4-Iodo-1,2,3-triazoles were synthesised via azide-alkyne cycloaddition of alkynyl Grignard reagent and benzyl azide followed by iodination reaction. The aminocarbonylation and aryloxycarbonylation of 4-iodo-1,2,3-triazoles were carried out in the presence of various N- and O-nucleophiles, resulting in the corresponding triazole-based 4-carboxamides and 4-esters, respectively. Both high-yielding reactions were carried out under mild conditions (atmospheric CO pressure, 70°C).
| Item Type: | Article |
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| Uncontrolled Keywords: | Aminocarbonylation; carbon monoxide; carbonylation; palladium; triazole |
| Subjects: | Q Science / természettudomány > QD Chemistry / kémia > QD04 Organic chemistry / szerves kémia |
| Depositing User: | Pap Viktória |
| Date Deposited: | 07 Apr 2021 07:13 |
| Last Modified: | 03 Apr 2023 07:12 |
| URI: | http://real.mtak.hu/id/eprint/123492 |
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