A novel conceptional approach for calculating the stability time related to converting the anticipated degradation from the curve of conductivity for flexible poly (vinyl chloride)

I.Al-Mosawi, Ali (2022) A novel conceptional approach for calculating the stability time related to converting the anticipated degradation from the curve of conductivity for flexible poly (vinyl chloride). ÉPÍTŐANYAG – JOURNAL OF SILICATE BASED AND COMPOSITE MATERIALS, 74 (5). pp. 188-195. ISSN 0013-970X (nyomtatott); 2064-4477 (online)

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Abstract

The current study introduces a novel method for calculating the stability time by a new approach based on the conversion of degradation from the conductivity curve results obtained by the conventional method. The stability time calculated by the novel method is shorter than the time measured by the conventional method. The stability time in the novel method can be calculated by the endpoint of the tangency of the conversion curve with the tangent line. This point of tangency represents the stability time, as will be explained in detail. Still, it gives a clear and accurate envisage of the dehydrochlorination behavior and can be generalized to all types of polyvinyl chloride compared to the stability time measured by conventional ones based on measuring the conductivity which cannot be used to compare different compounds because PVC-based compounds may include varying amounts of PVC. As a result, the conventional method is inapplicable in all cases. For example, specific conductivity of 60 µS/cm indicates the same quantity of HCl but a different degradation grade. If this conventional approach is used alone, the results obtained will be inaccurate. Therefore, the novel method possesses greater sensitivity and accuracy for these differences in PVC-based compounds.

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