Rawlinson, Jonathan I. and Fábri, Csaba and Császár, Attila Géza (2021) The rovibrational Aharonov-Bohm effect. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 23 (42). pp. 24154-24164. ISSN 1463-9076
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Abstract
Another manifestation of the Aharonov-Bohm effect is introduced to chemistry, in fact to nuclear quantum dynamics and high-resolution molecular spectroscopy. As demonstrated, the overall rotation of a symmetric-top molecule influences the dynamics of an internal vibrational motion in a way that is analogous to the presence of a solenoid carrying magnetic flux. To a good approximation, the low-energy rovibrational energy-level structure of the quasistructural molecular ion H+(5) can be understood entirely in terms of this effect.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science / természettudomány > QC Physics / fizika Q Science / természettudomány > QD Chemistry / kémia |
| SWORD Depositor: | MTMT SWORD |
| Depositing User: | MTMT SWORD |
| Date Deposited: | 19 Jan 2023 15:34 |
| Last Modified: | 19 Jan 2023 15:34 |
| URI: | http://real.mtak.hu/id/eprint/156890 |
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