Improving the mechanical and abrasion properties of silica-reinforced styrene-butadiene rubber composites by optimizing the concentrations of compatibilizers

Sayfo, Petra and Pölöskei, Kornél and Mészáros, László (2024) Improving the mechanical and abrasion properties of silica-reinforced styrene-butadiene rubber composites by optimizing the concentrations of compatibilizers. POLYMER BULLETIN, 81 (14). pp. 12715-12731. ISSN 0170-0839

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Abstract

Silica (chemical formula SiO2) is a promising, more environmentally friendly alternative to carbon black (CB) used in the rubber industry as a filler. Although silica is already used in rubber products, it is not used as extensively as CB because the polar surface of silica cannot interact well with the apolar polymer molecules of the most frequently used rubbers. To solve this problem, experts have tried different grafting methods and several coupling agents for a stronger silica-elastomer connection. In this article, we used bis[3-(triethoxysilyl)propyl] tetrasulfide (TESPT) and polyethylene glycol (PEG) combined to improve the connection between the surface of silica and the apolar styrene-butadiene rubber (SBR) matrix. We examined mechanical and structural properties and found that adding 3 phr PEG and 4.5 phr TESPT to SBR is optimal for 60 phr silica content. This ratio of additives resulted in a 48% improvement in tensile strength. The positive effect of the coupling agents shows up in abrasion mass loss and tear strength as well.

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