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Unveiling the True Identity of Carborane-Fused Phosphorus Heterocycles

Gál, Dalma and Szántai, Lóránt and Buzsáki, Dániel and Kelemen, Zsolt (2025) Unveiling the True Identity of Carborane-Fused Phosphorus Heterocycles. ORGANIC LETTERS, 27 (22). pp. 5637-5641. ISSN 1523-7060

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Abstract

In recent years, the possible global 2D/3D aromaticity of carborane-fused cycles has been widely debated. While phosphorus heterocycles fused with carboranes are known, the 2D aromatic character in carborane-fused phospholes was only recently reported. However, our computational study found that these compounds lack 2D aromaticity. Instead, they should be viewed not as a fusion of an aromatic ring but as a fusion of an unsaturated ring with carboranes.

Item Type: Article
Uncontrolled Keywords: Aromatic compounds, Aromaticity, Heterocyclic compounds, Phosphorus, Reaction products
Subjects: Q Science / természettudomány > Q1 Science (General) / természettudomány általában
Depositing User: Dr. Zsolt Kelemen
Date Deposited: 04 Sep 2025 08:17
Last Modified: 04 Sep 2025 08:17
URI: https://real.mtak.hu/id/eprint/223465

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