Review and Perspectives on the Sustainability of Organic Aerogels

García-Gonzáleza, Carlos A. and Blanco-Vales, María and Barros, Joana and Boccia, Antonella Caterina and Budtova, Tatiana and Durães, Luisa and Erkey, Can and Gallo, Marta and Herman, Petra and Kalmár, József and Iglesias-Mejuto, Ana and Malfait, Wim J. and Zhao, Shanyu and Manzocco, Lara and Plazzotta, Stella and Milovanovic, Stoja and Neagu, Monica and Nita, Loredana E. and Paraskevopoulou, Patrina and Roig, Anna and Simón-Vázquez, Rosana and Smirnova, Irina and Tomović, Željko and López-Iglesias, Clara (2025) Review and Perspectives on the Sustainability of Organic Aerogels. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 13 (18). pp. 6469-6492. ISSN 2168-0485

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Abstract

Aerogels are exceptionally lightweight materials characterized by their high open porosity and remarkable specific surface area, currently used across a wide array of industrial sectors from construction to energy storage and have great potential for expanding their applicability and unlocking new market opportunities. Driven by global economic growth and an intensifying environmental crisis, there is a growing demand for engineering innovations that prioritize sustainability. Aerogels are well-positioned to support these sustainability efforts. Their unique properties make them ideal for energy-saving solutions, environmental remediation, and more efficient use of resources. As the demand for eco-conscious technologies rises, aerogels are poised to contribute significantly to the development of greener, more efficient products and processes across multiple industries. The sustainability of aerogel technology is crucial for the mid-to-long-term future, yet its current status has been scarcely reviewed in the literature. This Perspective explores and critically reviews significant advances on organic and hybrid aerogels in the current socioeconomic scenario, with selected case studies endorsing their contribution to the UN Sustainable Development Goals. It also identifies research gaps while proposing innovative strategies to enhance the sustainability of aerogel production through the application of circular economy principles. Key strategies discussed involve the fabrication of aerogels using eco-friendly sources, such as biopolymers derived from biorefinery processes or from waste materials. Additionally, this Perspective examines the development of methods for the reuse, recycling, and end-of-life management of aerogels, along with the implementation of more efficient processing routes. Ultimately, this work highlights the need for comprehensive assessments of aerogel sustainability through life cycle assessment (LCA) and evaluations of safety and toxicity. By addressing these critical aspects, the potential of aerogels to contribute to a more sustainable future appears highly favorable from both commercial and research perspectives, paving the way for a circular aerogel economy and providing a lasting impact to the society in which we live.

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