Synthesis and utilization of α-aminophosphine oxides and related derivatives

Bálint, Erika and Tripolszky, Anna and Ádám, Anna and Tajti, Ádám and Keglevich, György (2016) Synthesis and utilization of α-aminophosphine oxides and related derivatives. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 191 (11-12). pp. 1539-1540. ISSN 1042-6507

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Abstract

Themicrowave-assisted synthesis of mono- and bis(aminophosphine oxides)was studied using various secondary phosphine oxides as the P-reagent in condensation with paraformaldehyde and primary amines. After double deoxygenation, the bis-products were utilized as bidentate phosphine ligands in the synthesis of platinum complexes. α-Aryl-α-aminophosphine oxides and α-aryl-α-aminophosphonates were also prepared by the addition of >P(O)H species to imines. © 2016 Taylor & Francis Group, LLC.

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