REAL

Multiple steady state in the hydrogenative ring opening of propylcyclobutane over Rh/SiO2

Pálinkó, István and Torok, B. (1997) Multiple steady state in the hydrogenative ring opening of propylcyclobutane over Rh/SiO2. CATALYSIS LETTERS, 45 (3-4). pp. 193-195. ISSN 1011-372X

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Abstract

During the hydrogenative ring-opening reaction of propylcyclobutane over Rh/SiO2 bifurcation was observed. On varying the hydrogen concentration in the reactor a catalytic surface with two steady states was formed. This bistability was found over the ''working'' catalyst and was attributed to the interplay of adsorbed hydrogen, adsorbed propylcyclobutane, the carbonaceous deposits and the surface or close to surface Rh atoms.

Item Type: Article
Subjects: Q Science / természettudomány > QD Chemistry / kémia
Q Science / természettudomány > QD Chemistry / kémia > QD02 Physical chemistry / fizikai kémia
SWORD Depositor: MTMT SWORD
Depositing User: MTMT SWORD
Date Deposited: 28 May 2013 13:48
Last Modified: 28 May 2013 13:48
URI: http://real.mtak.hu/id/eprint/5332

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