Chemical characterization of laboratory-generated tar ball particles

Tóth, Ádám and Hoffer, András and Pósfai, Mihály and Ajtai, Tibor and Kónya, Zoltán and Blazsó, Marianne and Czégény, Zsuzsanna and Kiss, Gyula and Bozóki, Zoltán and Gelencsér, András (2018) Chemical characterization of laboratory-generated tar ball particles. Atmospheric Chemistry and Physics, 18. pp. 10407-10418. ISSN 1680-7324

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Abstract

The chemical properties of laboratory-generated tar ball (Lab-TB) particles produced from dry distillate (wood tars) of three different wood species in the laboratory were investigated by analytical techniques that had never been used before for their characterization. The elemental compositions of laboratory-generated tar balls (Lab- TBs) from three tree species were very similar to one another and to those characteristic of atmospheric tar balls (TBs) collected from the savanna fire during the SAFARI 2000 sampling campaign. The O=C and H= C molar ratios of the generated Lab-TBs were at the upper limit characteristic of soot particles. The Fourier transform infrared spectroscopy (FTIR) spectra of the generated Lab-TBs were very similar to one another as well and also showed some similarity with those of atmospheric humic-like substances (HULIS). The FT-IR measurements indicated that Lab-TBs have a higher proportion of aromatic structure than HULIS and the oxygen atoms of Lab-TBs are mainly found in hydroxyl and keto functional groups. Whereas Raman activity was detected in the starting materials of the Lab-TBs (wood tars) in the range of 1000–1800 cm

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