Synthesis, optical and redox properties of regioisomeric benzoheterocycles- fused pyrene

Mocanu, Annabella and Szűcs, Rózsa and Caytan, Elsa and Roisnel, Thierry and Dorcet, Vincent and Bouit, Pierre-Antoine and Nyulászi, László and Hissler, Muriel (2019) Synthesis, optical and redox properties of regioisomeric benzoheterocycles- fused pyrene. JOURNAL OF ORGANIC CHEMISTRY, 84. pp. 957-962. ISSN 0022-3263

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Abstract

A new synthetic route toward the synthesis of benzo[b]phospholes and benzo[b]siloles-fused pyrenes using a transition metal-catalyzed C-H bond activation is described. The compounds were fully characterized including X-ray diffraction. A combined experimental and theoretical study shows that both the heteroatom and the substitution pattern impact the optical and redox properties.

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