Sadtler, V. M. and Jeanneaux, F. and Krafft, M. P. and Rábai, József and Riess, J. G. (1998) Perfluoroalkylated amphiphiles with a morpholinophosphate or a dimorpholinophosphate polar head group. NEW JOURNAL OF CHEMISTRY, 22 (6). pp. 609-613. ISSN 1144-0546
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Abstract
Some previously synthesized (perfluoroalkyl)alkyldimorpholinophosphates, CnF2n+1CmH2mOP(O)-[N(CH2CH2)(2)O](2), were found remarkably to stabilize heat sterilizable water-in-fluorocarbon reverse emulsions and to have a strong proclivity to self-aggregate into microtubular assemblies when dispersed in water. This series has now been extended in order to allow structure-property relationships to be established and product optimization to be achieved. A new series of even more fluorophilic compounds consisting in bis[(perfluoroalkyl)alkyl]monomorpholinophosphates, (CnF2n+1CmH2mO)(2)P(O)N(CH2CH2)(2)O, was also synthesized. Preliminary surfactant activity and biocompatibility data are presented and compared to data obtained with non-fluorinated analogues.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science / természettudomány > QD Chemistry / kémia > QD04 Organic chemistry / szerves kémia |
| SWORD Depositor: | MTMT SWORD |
| Depositing User: | MTMT SWORD |
| Date Deposited: | 31 Jul 2014 08:56 |
| Last Modified: | 31 Jul 2014 08:56 |
| URI: | http://real.mtak.hu/id/eprint/14018 |
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