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Shock-formed carbon materials with intergrown sp3- and sp2-bonded nanostructured units

Németh, Péter and Lancaster, Hector J. and Salzmann, Christoph G. and McColl, Kit and Fogarassy, Zsolt and Illés, Levente and Pécz, Béla (2022) Shock-formed carbon materials with intergrown sp3- and sp2-bonded nanostructured units. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES, 119 (30). e2203672119. ISSN 1091-6490

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Abstract

Diamond is the hardest material found in nature. Its applications range from abrasives and electronics to nanomedicine and laser technology. The common form of diamond is cubic. Yet, dense carbon materials formed by shock compression have been described as hexagonal diamond or lonsdaleite. This study provides a structural understanding of lonsdaleite and demonstrates the existence of bulk materials containing extensive regions of nanostructured diamond and graphene-like intergrowths called diaphites. The structural complexities found in Canyon Diablo iron meteorite diamonds occur in a wide range of carbonaceous materials, and their identification can place constraints on the pressure?temperature conditions experienced during an impact. The predicted advanced properties of such materials highlight their potential use in future engineering applications. Studies of dense carbon materials formed by bolide impacts or produced by laboratory compression provide key information on the high-pressure behavior of carbon and for identifying and designing unique structures for technological applications. However, a major obstacle to studying and designing these materials is an incomplete understanding of their fundamental structures. Here, we report the remarkable structural diversity of cubic/hexagonally (c/h) stacked diamond and their association with diamond-graphite nanocomposites containing sp3-/sp2-bonding patterns, i.e., diaphites, from hard carbon materials formed by shock impact of graphite in the Canyon Diablo iron meteorite. We show evidence for a range of intergrowth types and nanostructures containing unusually short (0.31 nm) graphene spacings and demonstrate that previously neglected or misinterpreted Raman bands can be associated with diaphite structures. Our study provides a structural understanding of the material known as lonsdaleite, previously described as hexagonal diamond, and extends this understanding to other natural and synthetic ultrahard carbon phases. The unique three-dimensional carbon architectures encountered in shock-formed samples can place constraints on the pressure?temperature conditions experienced during an impact and provide exceptional opportunities to engineer the properties of carbon nanocomposite materials and phase assemblages.

Item Type: Article
Subjects: Q Science / természettudomány > QC Physics / fizika
Q Science / természettudomány > QD Chemistry / kémia
SWORD Depositor: MTMT SWORD
Depositing User: MTMT SWORD
Date Deposited: 25 Jul 2022 06:06
Last Modified: 25 Jul 2022 06:06
URI: http://real.mtak.hu/id/eprint/145127

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