Ternary eutectic dendrites: Pattern formation and scaling properties

Rátkai, László and Szállás, Attila and Pusztai, Tamás and Mohri, T. and Gránásy, László (2015) Ternary eutectic dendrites: Pattern formation and scaling properties. JOURNAL OF CHEMICAL PHYSICS, 142 (15). ISSN 0021-9606

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Abstract

Extending previous work [T. Pusztai, L. R´atkai, A. Sz´all´as, and L. Gr´an´asy, Phys. Rev. E 87, 032402 (2013)], we have studied the formation of eutectic dendrites in a model ternary system within the frame- work of the phase-field theory. We have mapped out the domain in which two-phase dendritic structures grow. With increasing pulling velocity, the following sequence of growth morphologies is observed: flat front lamellae → eutectic colonies → eutectic dendrites → dendrites with target pattern → partitionless dendrites → partitionless flat front. We confirm that the two-phase and one-phase dendrites have similar forms, and display a similar scaling of the dendrite tip radius with the interface free energy. It is also found that the possible eutectic patterns include the target pattern, and single- and multiarm spirals, of which the thermal fluctuations choose. The most probable number of spiral arms increases with increasing tip radius and with decreasing kinetic anisotropy. Our numerical simulations confirm that in agreement with the assumptions of a recent analysis of two-phase dendrites [S. Akamatsu, S. Bottin-Rousseau, G. Faivre, and E. A. Brener, Phys. Rev. Lett. 112, 105502 (2014)], the Jackson-Hunt scaling of the eutectic wavelength with pulling velocity is obeyed in the parameter domain explored, and that the natural eutectic wavelength is proportional to the tip radius of the two-phase dendrites. Finally, we find that it is very difficult/virtually impossible to form spiraling two-phase dendrites without anisotropy, an observation that seems to contradict the expectations of Akamatsu et al.. Yet, it cannot be excluded, that in isotropic systems two-phase dendrites are rare events difficult to observe in simulations.

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