Pap, József Sándor and Szyrwiel, Łukasz and Srankó, Dávid Ferenc and Kerner, Zsolt Gábor and Setner, Bartosz and Szewczuk, Zbigniew and Malinka, Wiesław (2015) Electrocatalytic water oxidation by CuII complexes with branched peptides. CHEMICAL COMMUNICATIONS, 51 (29). pp. 6322-6324. ISSN 1359-7345
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Official URL: http://dx.doi.org/10.1039/c5cc00926j
Abstract
Two mononuclear CuII complexes with tetrapeptides incorporating a L-2,3-diaminopropionic acid (dap) branching unit are reported to undergo PCET and catalyse water oxidation. C-terminal His extension of dap (L = 2GH) instead of Gly (L = 3G) lowers the pKa for CuIIIH-2L (9.36 vs. 9.98) and improves the TOF at pH 11 (53 vs. 24 s-1).
| Item Type: | Article |
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| Subjects: | Q Science / természettudomány > QD Chemistry / kémia |
| Depositing User: | dr. József S Pap |
| Date Deposited: | 25 Sep 2015 12:49 |
| Last Modified: | 31 Mar 2016 23:15 |
| URI: | http://real.mtak.hu/id/eprint/27997 |
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