Szabó, Fruzsina and Darú, János and Simkó, Dániel and Nagy, Tibor Zs. and Stirling, András and Novák, Zoltán (2013) Mild Palladium-Catalyzed Oxidative Direct ortho-C H Acylation of Anilides under Aqueous Conditions. Advanced Synthesis and Catalysis, 355. pp. 685-691. ISSN 1615-4150
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/adsc.20...
Abstract
Palladium-catalyzed cross-dehydrogenative coupling between anilides and aromatic aldehydes was achieved under aqueous conditions. A wide variety of the desired benzophenone derivatives was isolated in good to excellent yield. The reaction rate acceleration effect of acid and detergent has been demonstrated. Mechanistic insight has been obtained from quantum chemical calculations.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science / természettudomány > Q1 Science (General) / természettudomány általában Q Science / természettudomány > QD Chemistry / kémia Q Science / természettudomány > QD Chemistry / kémia > QD04 Organic chemistry / szerves kémia |
| Depositing User: | Dr. xAranka xPilbáth |
| Date Deposited: | 17 May 2013 13:09 |
| Last Modified: | 23 Jul 2013 12:06 |
| URI: | http://real.mtak.hu/id/eprint/5164 |
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