REAL

Deuterium distribution in two major products obtained during the cyclic dimerisation of methyloxirane over acidic molecular sieves

Fási, András and Pálinkó, István (2006) Deuterium distribution in two major products obtained during the cyclic dimerisation of methyloxirane over acidic molecular sieves. In: Sampling catalysis research in the Pannonian region: proceedings of the 8th Pannonian International Catalysis Symposium. Hungarian Zeolite Association, Szeged, pp. 37-42. ISBN 963-06-0138-9

[img]
Preview
Text
1144458.pdf

Download (278kB) | Preview

Abstract

The ring-transformation reactions of methyloxirane on DZSM-5 and DAlMCM-41 aluminosilicates were studied in a pulse microreactor at 363 K. Cyclic dimerisation was found to be the major reaction pathway. Deuterium distribution in two important products of this reaction route was monitored. The positions of the deuterium atoms were determined giving help in proposing a more accurate dimerisation mechanism.

Item Type: Book Section
Subjects: Q Science / természettudomány > QD Chemistry / kémia
Q Science / természettudomány > QD Chemistry / kémia > QD02 Physical chemistry / fizikai kémia
Q Science / természettudomány > QD Chemistry / kémia > QD04 Organic chemistry / szerves kémia
Depositing User: Erika Bilicsi
Date Deposited: 03 Jun 2013 09:41
Last Modified: 03 Jun 2013 09:41
URI: http://real.mtak.hu/id/eprint/5441

Actions (login required)

Edit Item Edit Item