Bojtár, Márton and Simon, András and Bombicz, Petra and Bitter, István (2017) Expanding the Pillararene Chemistry: Synthesis and Application of a 10 + 1 Functionalized Pillar[5]arene. Organic Letters, 19 (17). pp. 4528-4531. ISSN 1523-7060
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Abstract
A novel functionality was introduced in the pillararene family by the Claisen rearrangement of monoallyl pillar[5]arene. This new key derivative can lead to the formation of a 10 + 1 functionalized derivative, a useful scaffold for further derivatization. Except for the previously known monodeprotection reaction, all steps proceed efficiently with high yields and easy separation. In addition, a solvent-responsive pseudo[1]rotaxane was synthesized based on this novel functionality.
| Item Type: | Article |
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| Subjects: | Q Science / természettudomány > QD Chemistry / kémia Q Science / természettudomány > QD Chemistry / kémia > QD04 Organic chemistry / szerves kémia |
| Depositing User: | Márton Bojtár |
| Date Deposited: | 14 Sep 2017 13:17 |
| Last Modified: | 01 Sep 2018 23:15 |
| URI: | http://real.mtak.hu/id/eprint/62393 |
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