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Fluorine-Containing Functionalized Cyclopentene Scaffolds Through Ring Contraction and Deoxofluorination of Various Substituted Cyclohexenes

Rermete, Attila and Nonn, Melinda and Fustero, Santos and Haukka, Matti and Fülöp, Ferenc and Kiss, Loránd (2018) Fluorine-Containing Functionalized Cyclopentene Scaffolds Through Ring Contraction and Deoxofluorination of Various Substituted Cyclohexenes. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. pp. 3735-3742. ISSN 1434-193X

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Abstract

The fluorination of some highly-functionalized cyclopentene derivatives, obtained from various substituted cyclohexenes through a ring-opening/ring-contraction procedure, has been investigated. The transformations were found to be highly substrate dependent, and led to the formation of various functionalized alicyclic compounds or heterocycles containing allyl difluoride or vinyl fluoride moieties.

Item Type: Article
Subjects: Q Science / természettudomány > QD Chemistry / kémia > QD04 Organic chemistry / szerves kémia
Depositing User: Dr Loránd Kiss
Date Deposited: 19 Nov 2018 10:15
Last Modified: 19 Nov 2018 10:15
URI: http://real.mtak.hu/id/eprint/87161

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