Effect of molecular architecture on the crystalline structure and stiffness of iPP homopolymers: modeling based on annealing experiments

Horváth, Zsuzsanna and Menyhárd, Alfréd and Doshev, Petar and Gahleitner, Marcus and Tranninger, Cornelia and Kheirandish, Saeid and Varga, József and Pukánszky, Béla (2013) Effect of molecular architecture on the crystalline structure and stiffness of iPP homopolymers: modeling based on annealing experiments. Journal of Applied Polymer Science, 130 (5). pp. 3365-3373. ISSN 0021-8995

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Abstract

Five PP homopolymers were selected and their molecular structure was thoroughly characterized to determine the effect of molecular architecture on their annealing behavior and on the ultimate stiffness achieved by heat treatment. Molecular mass and its distribution were characterized by rheological measurements, while chain regularity was determined by calorimetry, by the stepwise isothermal segregation technique (SIST). The samples were annealed in two different ways. Tensile bars were treated in an oven at 165 °C for increasing times to determine changes in stiffness. Various defects developed during the annealing of tensile specimens that did not allow the reliable determination of modulus by direct measurement. On the other hand, the second approach, the annealing of small samples in a DSC cell clearly showed the changes occurring in crystalline structure and also the effect of nucleation and molecular architecture on them. The large molecular weight fraction used to facilitate nucleation hinders crystal perfection, while the presence of a heterogeneous nucleating agent increases overall crystallinity, but does not influence recrystallization during annealing. Melting traces were transformed into lamella thickness distributions, from which average lamella thickness was derived. Lamella thickness and crystallinity, the independent variables of the empirical equation used for the calculation of modulus, were extrapolated to infinite annealing time to predict maximum stiffness. The value obtained, 3.5 GPa, is very far from the theoretically predicted 40 GPa of oriented crystals, which cannot be achieved under practical conditions.

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