Adsorption of Aromatic Hydrocarbon Molecules at the Surface of Ice, As Seen by Grand Canonical Monte Carlo Simulation

Meszar, Z. E. and Hantal, G. and Picaud, S. and Jedlovszky, Pál (2013) Adsorption of Aromatic Hydrocarbon Molecules at the Surface of Ice, As Seen by Grand Canonical Monte Carlo Simulation. JOURNAL OF PHYSICAL CHEMISTRY C - NANOMATERIALS AND INTERFACES, 117 (13). pp. 6719-6729. ISSN 1932-7447

Text Adsorption of Aromatic Hydrocarbon Molecules at the Surface of Ice_REAL.pdf Restricted to Repository staff only Download (3MB) | Request a copy

Abstract

The adsorption of four aromatic hydrocarbon compounds, benzene, naphthalene, anthracene, and phenanthrene, at the surface of I-h ice is investigated by grand canonical Monte Carlo (GCMC) computer simulation under tropospheric conditions at 200 K. By systematic variation of the value of adsorbate chemical potential in the simulations, the adsorption isotherms are determined, It is found that adsorption follows the Langmuir mechanism only up to a rather low relative pressure value in every case. In this range specific surface sites, called alpha sites, to which adsorbate molecules can be bound particularly strongly in specific orientation, are occupied. In these alpha sites, presumably the dangling OH bonds of the ice surface form O-H-center dot center dot center dot center dot pi-type hydrogen bonds with the delocalized pi electrons of the adsorbed aromatic molecule lying parallel with the ice surface. Once these alpha sites are saturated, lateral interactions become increasingly important, leading to large fluctuations of the lateral density of the adsorption layer and an increasing deviation of the adsorption isotherm from the Langmuir shape. The adsorption layer is found to be strictly monomolecular and even unsaturated in every case, as condensation well precedes the saturation of this monolayer for all four aromatic adsorbates considered in this study.

Actions (login required)

Edit Item