A systematic mid-infrared spectroscopic study of thermally processed H2S ices

Mifsud, Duncan and Herczku, Péter and Ramachandran, Ragav and Sundararajan, Pavithraa and Kumar Kushwaha, Rahul and Kovács, Sándor and Sulik, Béla and Juhász, Zoltán and Rácz, Richárd Péter and Biri, Sándor and Kaňuchová, Zuzana and Ioppolo, Sergio and Sivaraman, Bhalamurugan and McCullough, Robert W. and Mason, Nigel J. (2024) A systematic mid-infrared spectroscopic study of thermally processed H2S ices. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 319. No. 124567. ISSN 1386-1425

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Abstract

The positive identification of the molecular components of interstellar icy grain mantles is critically reliant upon the availability of laboratory-generated mid-infrared absorption spectra which can be compared against data acquired by ground- and space-borne telescopes. However, one molecule which remains thus far undetected in interstellar ices is H2S, despite its important roles in astrochemical and geophysical processes. Such a lack of a detection is surprising, particularly in light of its relative abundance in cometary ices which are believed to be the most pristine remnants of pre-solar interstellar ices available for study. In this paper, we present the results of an extensive and quantitative mid-infrared spectroscopic characterisation of H2S ices deposited at 20, 40, and 70 K and thermally processed to sublimation in an ultrahigh-vacuum system. We anticipate our results to be useful in confirming the detection of interstellar H2S ice using high-resolution and high-sensitivity instruments such as the James Webb Space Telescope, as well as in the identification of solid H2S in icy environments in the outer Solar System, such as comets and moons.

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